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First synthesis of naphthalene annulated oxepins

URN to cite this document:
urn:nbn:de:bvb:355-epub-309652
DOI to cite this document:
10.5283/epub.30965
Dobelmann, Lars ; Parham, A. H. ; Büsing, A. ; Buchholz, H. ; König, Burkhard
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License: Creative Commons: Attribution 3.0
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Date of publication of this fulltext: 17 Nov 2014 07:09


Abstract

Highly condensed oxepins have been prepared in good yields from their corresponding diols by etherification using p-toluenesulfonic acid. Their intriguing twisted structures were unambiguously determined by X-ray crystallography. Substitution effects of a novel highly aromatic naphthalene annulated oxepin indicate that structural and conjugative effects have an influence on the optoelectronic properties.


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