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About the polymorphism of Li(C4H8O)3I: crystal structures of trigonal and tetragonal polymorphs

Gärtner, Stefanie, Gärtner, Tobias, Gschwind, Ruth Maria and Korber, Nikolaus (2014) About the polymorphism of Li(C4H8O)3I: crystal structures of trigonal and tetragonal polymorphs. Acta Crystallographica Section E 70 (12), pp. 555-558.

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Abstract

Two new trigonal and tetragonal polymorphs of the title compound, iodidotris(tetrahydrofuran-kappaO)lithium, are presented, which both include the isolated ion pair Li(THF)3+.I-. One Li-I ion contact and three tetrahydrofuran (THF) molecules complete the tetrahedral coordination of the lithium cation. The three-dimensional arrangement in the two polymorphs differs notably. In the trigonal ...

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Item type:Article
Date:2014
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1107/S160053681402529XDOI
Keywords:crystal structure; polymorphism; THF solvate; lithium complexes
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:30998
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