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About the polymorphism of Li(C4H8O)3I: crystal structures of trigonal and tetragonal polymorphs

Gärtner, Stefanie ; Gärtner, Tobias ; Gschwind, Ruth Maria ; Korber, Nikolaus


Two new trigonal and tetragonal polymorphs of the title compound, iodidotris(tetrahydrofuran-kappaO)lithium, are presented, which both include the isolated ion pair Li(THF)3+.I-. One Li-I ion contact and three tetrahydrofuran (THF) molecules complete the tetrahedral coordination of the lithium cation. The three-dimensional arrangement in the two polymorphs differs notably. In the trigonal ...


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