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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-312402
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.31240
Zusammenfassung
The chemoselective photoreduction of aldehydes in the presence of ketones was achieved using triethanolamine (TEOA) as sacrificial electron donor, proflavine (PF) as photocatalyst and [Cp*Rh(III)(bpy) Cl]Cl (Rhcat) as mediator. The reducing agent, which reacts with the carbonyl group was found to be [Cp*Rh(III)(bpy)H]Cl (Rh(III)–H). Contrary to formate-based reduction, its slow photochemical in ...
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