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Visible light photocatalytic reduction of aldehydes by Rh(III)–H: a detailed mechanistic study

Ghosh, Tamal, Slanina, Tomas and König, Burkhard (2015) Visible light photocatalytic reduction of aldehydes by Rh(III)–H: a detailed mechanistic study. Chemical Science 6, pp. 2027-2034.

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Date of publication of this fulltext: 22 Jan 2015 12:35

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Abstract

The chemoselective photoreduction of aldehydes in the presence of ketones was achieved using triethanolamine (TEOA) as sacrificial electron donor, proflavine (PF) as photocatalyst and [Cp*Rh(III)(bpy) Cl]Cl (Rhcat) as mediator. The reducing agent, which reacts with the carbonyl group was found to be [Cp*Rh(III)(bpy)H]Cl (Rh(III)–H). Contrary to formate-based reduction, its slow photochemical in ...

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Item type:Article
Date:2015
Additional Information (public):Open Access Komponente aus der Allianzlizenz
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1039/c4sc03709jDOI
Related URLs:
URLURL Type
http://pubs.rsc.org/en/Content/ArticleLanding/2015/SC/C4SC03709J#!divAbstractUNSPECIFIED
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:31240
Owner only: item control page

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