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Visible light photocatalytic reduction of aldehydes by Rh(III)–H: a detailed mechanistic study

URN to cite this document:
urn:nbn:de:bvb:355-epub-312402
Ghosh, Tamal ; Slanina, Tomas ; König, Burkhard
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Date of publication of this fulltext: 22 Jan 2015 12:35


Abstract

The chemoselective photoreduction of aldehydes in the presence of ketones was achieved using triethanolamine (TEOA) as sacrificial electron donor, proflavine (PF) as photocatalyst and [Cp*Rh(III)(bpy) Cl]Cl (Rhcat) as mediator. The reducing agent, which reacts with the carbonyl group was found to be [Cp*Rh(III)(bpy)H]Cl (Rh(III)–H). Contrary to formate-based reduction, its slow photochemical in ...

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