Synthesis, Structural Characterization, and Physical Properties of Cs2Ga2S5, and Redetermination of the Crystal Structure of Cs2S6

URN to cite this document:: urn:nbn:de:bvb:355-epub-312592
DOI to cite this document:: 10.5283/epub.31259

Friedrich, D.

; Pielnhofer, F.

; Schlosser, Marc

; Weihrich, Richard ; Pfitzner, Arno

Preview

PDF
(777kB)

Date of publication of this fulltext: 02 Feb 2015 13:00

Alternative links to fulltext:DOI

Details

Preview

Indexed in

Export bibliographical data

Abstract

The reaction of CsN3 with GaS and S at elevated temperatures results in Cs2Ga2S5. Its crystal structure was determined from single-crystal X-ray diffraction data. The colorless solid crystallizes in space group C2/c (no. 15) with V=1073.3(4) angstrom(3) and Z=4. Cs2Ga2S5 is the first compound that features one-dimensional chains (1)(infinity)[Ga2S3(S-2)(2-)] of edge- and corner-sharing GaS4 ...