Go to content
UR Home

Synthesis, Structural Characterization, and Physical Properties of Cs2Ga2S5, and Redetermination of the Crystal Structure of Cs2S6

URN to cite this document:
urn:nbn:de:bvb:355-epub-312592
Friedrich, D. ; Pielnhofer, F. ; Schlosser, Marc ; Weihrich, Richard ; Pfitzner, Arno
[img]
Preview
PDF
(777kB)
Date of publication of this fulltext: 02 Feb 2015 13:00


Abstract

The reaction of CsN3 with GaS and S at elevated temperatures results in Cs2Ga2S5. Its crystal structure was determined from single-crystal X-ray diffraction data. The colorless solid crystallizes in space group C2/c (no. 15) with V=1073.3(4) Å3 and Z=4. Cs2Ga2S5 is the first compound that features one-dimensional chains equation image[Ga2S3(S2)2−] of edge- and corner-sharing GaS4 tetrahedra. The ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons