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Specific ion adsorption on alkyl carboxylate surfactant layers

Dengler, Susanne ; Tiddy, Gordon J. T. ; Zahnweh, Lydia ; Kunz, Werner



Abstract

Mixtures of dodecyl carboxylate, CsOH, RbOH and octanol in D2O were investigated to determine the relative ion specificity of Cs+ and Rb+ in their interactions with dodecyl carboxylate in a liquid crystalline phase. Octanol as cosurfactant was necessary to obtain the lamellar liquid crystalline phase. The technique used was the measurement of the NMR quadrupole splitting of Cs-137 and Rb-87. The ...

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