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Visible light photooxidation of nitrate: the dawn of a nocturnal radical

Hering, Thea, Slanina, Tomas, Hancock, A., Wille, U. and König, Burkhard (2015) Visible light photooxidation of nitrate: the dawn of a nocturnal radical. Chemical Communications 51, pp. 6568-6571.

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Date of publication of this fulltext: 19 Mar 2015 13:58

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Abstract

Highly oxidizing nitrate radicals (NO3°) are easily accessed from readily available nitrate salts by visible light photoredox catalysis using a purely organic dye as the catalyst and oxygen as the terminal oxidant. The interaction of the excited catalyst and nitrate anions was studied by spectroscopic methods to elucidate the mechanism, and the method was applied to the NO3° induced oxidation of alkynes and alcohols.


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Item type:Article
Date:2015
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1039/c5cc01580dDOI
Keywords:Open Access Komponente aus der Allianzlizenz
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:31487
Owner only: item control page

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