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Tunable Porosities and Shapes of Fullerene-Like Spheres

Dielmann, F. ; Fleischmann, M. ; Heindl, C. ; Peresypkina, E. V. ; Virovets, A. V. ; Gschwind, R. M. ; Scheer, Manfred


The formation of reversible switchable nanostructures monitored by solution and solid-state methods is still a challenge in supramolecular chemistry. By a comprehensive solid state and solution study we demonstrate the potential of the fivefold symmetrical building block of pentaphosphaferrocene in combination with CuI halides to switch between spheres of different porosity and shape. With ...


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