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Intermolecular Formyloxyarylation of Alkenes by Photoredox Meerwein Reaction

Yao, Chang Jiang, Sun, Qiu, Rastogi, Namrata and König, Burkhard (2015) Intermolecular Formyloxyarylation of Alkenes by Photoredox Meerwein Reaction. ACS Catalysis 5, pp. 2935-2938.

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Abstract

The intermolecular formyloxylation−arylation of stilbenes occurs in the presence of diazonium salts, a photocatalyst, visible light, and DMF. The photo-Meerwein addition products are obtained in good yields up to 76%. We propose the formation of an iminium ion intermediate, which is hydrolyzed to the product


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Item type:Article
Date:2015
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1021/acscatal.5b00314DOI
Keywords:formyloxylation-arylation, Meerwein reaction, photocatalysis, diazonium salts, N,N-dimethylformamide
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:31642
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