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Pöllmann, Christoph ; Steinleitner, Philipp ; Leierseder, Ursula ; Nagler, Philipp ; Plechinger, Gerd ; Porer, Michael ; Bratschitsch, R. ; Schüller, Christian ; Korn, Tobias ; Huber, Rupert

Resonant internal Quantum transitions and femtosecond radiative decay of excitons in monolayer WSe2

Pöllmann, Christoph, Steinleitner, Philipp, Leierseder, Ursula, Nagler, Philipp, Plechinger, Gerd, Porer, Michael, Bratschitsch, R. , Schüller, Christian, Korn, Tobias und Huber, Rupert (2015) Resonant internal Quantum transitions and femtosecond radiative decay of excitons in monolayer WSe2. Nature Materials 14, S. 889-894.

Veröffentlichungsdatum dieses Volltextes: 24 Jul 2015 11:50
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.32244


Zusammenfassung

Atomically thin two-dimensional crystals have revolutionized materials science(1-3). In particular, monolayer transition metal dichalcogenides promise novel optoelectronic applications, owing to their direct energy gaps in the optical range(4-9). Their electronic and optical properties are dominated by Coulomb-bound electron-hole pairs called excitons(10-18), whose unusual internal structure(13), ...

Atomically thin two-dimensional crystals have revolutionized materials science(1-3). In particular, monolayer transition metal dichalcogenides promise novel optoelectronic applications, owing to their direct energy gaps in the optical range(4-9). Their electronic and optical properties are dominated by Coulomb-bound electron-hole pairs called excitons(10-18), whose unusual internal structure(13), symmetry(15-17), many-body effects(18) and dynamics have been vividly discussed. Here we report the first direct experimental access to all 1s A excitons, regardless of momentum-inside and outside the radiative cone-in single-layerWSe(2). Phase-locked mid-infrared pulses reveal the internal orbital 1s-2p resonance, which is highly sensitive to the shape of the excitonic envelope functions and provides accurate transition energies, oscillator strengths, densities and linewidths. Remarkably, the observed decay dynamics indicates an ultrafast radiative annihilation of small-momentum excitons within 150 fs, whereas Auger recombination prevails for optically dark states. The results provide a comprehensive view of excitons and introduce a new degree of freedom for quantum control, optoelectronics and valleytronics of dichalcogenide monolayers(19-24).



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftNature Materials
Verlag:NATURE PUBLISHING GROUP
Ort der Veröffentlichung:LONDON
Band:14
Seitenbereich:S. 889-894
Datum13 Juli 2015
InstitutionenPhysik > Institut für Experimentelle und Angewandte Physik > Lehrstuhl Professor Huber > Arbeitsgruppe Rupert Huber
Physik > Institut für Experimentelle und Angewandte Physik > Lehrstuhl Professor Lupton > Arbeitsgruppe Christian Schüller
Identifikationsnummer
WertTyp
10.1038/NMAT4356DOI
Stichwörter / Keywords2-DIMENSIONAL MATERIALS; VALLEY POLARIZATION; GENERATION; MOS2; PHOTOLUMINESCENCE;
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
Dokumenten-ID32244

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