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Visible Light-Mediated Metal-Free Synthesis of Vinyl Sulfones from Aryl Sulfinates

Meyer, Andreas Uwe ; Jäger, Stefanie ; Hari, Durga Prasad ; König, Burkhard


Visible light and eosin Y catalyze the synthesis of vinyl sulfones from aryl sulfinates and alkenes by a photoredox process. The reaction scope is broad in aryl sulfinates and alkenes and the general and simple procedure provides a metal-free alternative for the synthesis of synthetically valuable vinyl sulfones.

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