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Diels–Alder hydrogels for controlled antibody release: Correlation between mesh size and release rate

Kirchhof, Susanne ; Abrami, Michela ; Messmann, Viktoria ; Hammer, Nadine ; Goepferich, Achim ; Grassi, Mario ; Brandl, Ferdinand


Eight-armed PEG, molecular mass 10 kDa, was functionalized with furyl and maleimide groups, respectively; the obtained macromonomers were cross-linked via Diels–Alder chemistry. The mesh size (ξ) of the prepared hydrogels was determined by swelling studies, rheology, and low field NMR spectroscopy. The in vitro release of fluorescein isothiocyanate labeled dextrans (FDs) and bevacizumab was ...


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