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Metal‐Free Perfluoroarylation by Visible Light Photoredox Catalysis

Meyer, Andreas Uwe ; Slanina, Tomas ; Yao, Chang Jiang ; König, Burkhard


Visible light and eosin Y catalyze the direct arylation of simple arenes with fluorinated aryl bromides by a photoredox process. The reaction scope is broad in fluorinated compounds and arenes and the general and simple procedure provides a metal-free alternative for the synthesis of synthetically valuable polyfluorinated biaryl structures. The mild reaction conditions allow a selective reaction ...


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