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Metal‐Free Perfluoroarylation by Visible Light Photoredox Catalysis

Meyer, Andreas Uwe, Slanina, Tomas, Yao, Chang Jiang and König, Burkhard (2016) Metal‐Free Perfluoroarylation by Visible Light Photoredox Catalysis. ACS Catalysis 6, pp. 369-375.

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Abstract

Visible light and eosin Y catalyze the direct arylation of simple arenes with fluorinated aryl bromides by a photoredox process. The reaction scope is broad in fluorinated compounds and arenes and the general and simple procedure provides a metal-free alternative for the synthesis of synthetically valuable polyfluorinated biaryl structures. The mild reaction conditions allow a selective reaction ...

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Item type:Article
Date:2016
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1021/acscatal.5b02410DOI
Keywords:Perfluorophenyl; photocatalysis; visible light; metal-free conditions; C-H arylation; transient spectroscopy
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:33025
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