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Synthesis and Reactivity of Lewis Base Stabilized Pnictogenylboranes

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Marquardt, Christian
Date of publication of this fulltext: 12 Dec 2016 06:19

Abstract (English)

This thesis deals with the synthesis of pnictogenylboranes and a detailed study of their reactivity. For the first time a Lewis base stabilized stibanylborane of the type H2SbBH2·LB (LB = Lewis base) was synthesized and completely characterized. A new route to substituted phosphanylboranes was developed and they were used for the generation of polymers and gave access to the first example of a ...


Translation of the abstract (German)

Die vorliegende Arbeit behandelt die Synthese von Pnictogenylboranen und eine detaillierte Untersuchung deren Reaktivität. Zum ersten Mal konnte ein Lewis-Base-stabilisiertes Stibanylboran des Typs H2SbBH2·LB (LB = Lewis-Base) dargestellt und komplett charakterisiert werden. Ein neuer Zugang zu substituierten Phosphanylboranen wurde entwickelt und diese wurden zur Synthese von Polymeren ...


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