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Gieshoff, Tim N. ; Villa, Matteo ; Welther, Alice ; Plois, Markus ; Chakraborty, Uttam ; Wolf, Robert ; Jacobi von Wangelin, Axel

Iron-catalyzed olefin hydrogenation at 1 bar H2 with a FeCl3–LiAlH4 catalyst

Article

Gieshoff, Tim N., Villa, Matteo, Welther, Alice, Plois, Markus, Chakraborty, Uttam, Wolf, Robert and Jacobi von Wangelin, Axel (2015) Iron-catalyzed olefin hydrogenation at 1 bar H2 with a FeCl3–LiAlH4 catalyst. Green Chemistry 17, pp. 1408-1413.

DOI to cite this document: 10.5283/epub.33290


Abstract

The scope and mechanism of a practical protocol for the iron-catalyzed hydrogenation of alkenes and alkynes at 1 bar H2 pressure were studied. The catalyst is formed from cheap chemicals (5 mol% FeCl3–LiAlH4, THF). A homogeneous mechanism operates at early stages of the reaction while active nanoparticles form upon ageing of the catalyst solution.



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Details

Item typeArticle
Journal or Publication TitleGreen Chemistry
PublisherRoyal Society of Chemistry (RSC)
Volume17
Page Rangepp. 1408-1413
Date2015
Date of publication12 Feb 2016 11:04
Additional Information (public)Open Access Komponente aus der Allianzlizenz
InstitutionsChemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf
Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Arbeitskreis Prof. Dr. Axel Jacobi von Wangelin
Identification Number
ValueType
10.1039/C4GC02368DDOI
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-332908
Item ID33290

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