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Synthesis of arsenic-rich Asn ligand complexes from yellow arsenic

Graßl, Christian, Bodensteiner, Michael, Zabel, Manfred and Scheer, Manfred (2015) Synthesis of arsenic-rich Asn ligand complexes from yellow arsenic. Chemical Science (Chem. Sci.) 6, pp. 1379-1382.

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Abstract

The reaction of [{η5-Cp′′′Co}2{μ,η4:4-toluene}] with yellow arsenic yields the arsenic-rich Asn ligand complexes [{Cp′′′Co(μ,η2:2-As2)}2] (1), [(Cp′′′Co)4(μ4,η4:4:2:2:1:1-As10)] (2) and [(Cp′′′Co)3(μ3,η4:4:2:1-As12)] (3), which were comprehensively characterized. The molecular structure of 1 show a triple-decker complex with two As2 units forming the middle-deck; compound 2 contains an ...

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Item type:Article
Date:2015
Additional Information (public):Open Access Komponente aus der Allianzlizenz
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Identification Number:
ValueType
10.1039/C4SC03543GDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33307
Owner only: item control page

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