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Synthesis of arsenic-rich Asn ligand complexes from yellow arsenic

URN to cite this document:
urn:nbn:de:bvb:355-epub-333077
Graßl, Christian ; Bodensteiner, Michael ; Zabel, Manfred ; Scheer, Manfred
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Date of publication of this fulltext: 16 Feb 2016 10:05


Abstract

The reaction of [{η5-Cp′′′Co}2{μ,η4:4-toluene}] with yellow arsenic yields the arsenic-rich Asn ligand complexes [{Cp′′′Co(μ,η2:2-As2)}2] (1), [(Cp′′′Co)4(μ4,η4:4:2:2:1:1-As10)] (2) and [(Cp′′′Co)3(μ3,η4:4:2:1-As12)] (3), which were comprehensively characterized. The molecular structure of 1 show a triple-decker complex with two As2 units forming the middle-deck; compound 2 contains an ...

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