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- URN zum Zitieren dieses Dokuments:
- urn:nbn:de:bvb:355-epub-333113
- DOI zum Zitieren dieses Dokuments:
- 10.5283/epub.33311
Zusammenfassung
Thermolysis of [CpMn(η⁶-cht)] with P₄ in 1,3-diisopropylbenzene leads to the formation of the heterocubane [Cp₄Mn₄P₄] (1) in high yields, as a rare example of ‘naked’ phosphorus containing complexes of manganese. Compound 1 is characterized and studied by DFT calculations and reflection measurements. 1D coordination polymers [{(CpMn)₄(μ₃-P)₄}(CuX)]n (2-Cl: X = Cl; 2-Br: X = Br) are obtained in ...
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