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No photocatalyst required – versatile, visible light mediated transformations with polyhalomethanes

URN to cite this document:
urn:nbn:de:bvb:355-epub-333165
Franz, Johannes F. ; Kraus, Wolfgang B. ; Zeitler, Kirsten
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Date of publication of this fulltext: 19 Feb 2016 14:18


Abstract

A visible light mediated, but photocatalyst-free method for the oxidative α-CH functionalization of tertiary amines with a broad scope of carbon- and heteroatom nucleophiles using polyhalomethanes has been developed. In addition, the pivotal visible light triggered activation of polyhalomethanes offers mild conditions for efficient Kharasch-type additions onto non-activated olefins. Preliminary mechanistic studies are reported.


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