Franz, Johannes F., Kraus, Wolfgang B. and Zeitler, Kirsten (2015) No photocatalyst required – versatile, visible light mediated transformations with polyhalomethanes. Chemical Communications 51, pp. 8280-8283.
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Abstract
A visible light mediated, but photocatalyst-free method for the oxidative α-CH functionalization of tertiary amines with a broad scope of carbon- and heteroatom nucleophiles using polyhalomethanes has been developed. In addition, the pivotal visible light triggered activation of polyhalomethanes offers mild conditions for efficient Kharasch-type additions onto non-activated olefins. Preliminary mechanistic studies are reported.
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| Item type: | Article | ||||
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| Date: | 2015 | ||||
| Additional Information (public): | Open Access Komponente aus der Allianzlizenz | ||||
| Institutions: | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Robert Wolf Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors > Arbeitskreis Dr. Kirsten Zeitler Chemistry and Pharmacy > Institut für Organische Chemie > Alumni or Retired Professors | ||||
| Identification Number: |
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| Dewey Decimal Classification: | 500 Science > 540 Chemistry & allied sciences | ||||
| Status: | Published | ||||
| Refereed: | Yes, this version has been refereed | ||||
| Created at the University of Regensburg: | Yes | ||||
| Item ID: | 33316 |
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