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- URN to cite this document:
- urn:nbn:de:bvb:355-epub-333165
- DOI to cite this document:
- 10.5283/epub.33316
Alternative links to fulltext:DOI
Abstract
A visible light mediated, but photocatalyst-free method for the oxidative α-CH functionalization of tertiary amines with a broad scope of carbon- and heteroatom nucleophiles using polyhalomethanes has been developed. In addition, the pivotal visible light triggered activation of polyhalomethanes offers mild conditions for efficient Kharasch-type additions onto non-activated olefins. Preliminary mechanistic studies are reported.
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