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Tuneable anisotropy and magnetism in Sn2Co3S2–xSex – probed by 119Sn Mößbauer Spectroscopy and DFT studies

Weihrich, Richard, Yan, W., Rothballer, J., Peter, Ph., Rommel, S., Haumann, S., Winter, F., Schwickert, Ch. and Pöttgen, R. (2015) Tuneable anisotropy and magnetism in Sn2Co3S2–xSex – probed by 119Sn Mößbauer Spectroscopy and DFT studies. Dalton Transactions 44, pp. 15855-15864.

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Abstract

The half metal (HFM) Sn2Co3S2 shows a fascinating S = 1/2 magnetism. Anisotropic coupling of spins in and between Co Kagomé layers by Sn sites is now studied from the substitution effects of S by Se by systematic and local experimental and first principles data. Trends in crystal structure changes (c/a ratio) as retrieved from XRD data on the solid solution Sn2Co3S2−xSex are complemented by DFT ...

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Item type:Article
Date:2015
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Dr. Richard Weihrich
Identification Number:
ValueType
10.1039/C5DT02036KDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33475
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