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Control of Reactivity and Regioselectivity for On-Surface Dehydrogenative Aryl-Aryl Bond Formation.

Kocić, Nemanja, Liu, Xunshan, Chen, Songjie, Decurtins, Silvio, Krejčí, Ondřej, Jelínek, Pavel, Repp, Jascha and Liu, Shi-Xia (2016) Control of Reactivity and Regioselectivity for On-Surface Dehydrogenative Aryl-Aryl Bond Formation. Journal of the American Chemical Society 138 (17), pp. 5585-5593.

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Abstract

Regioselectivity is of fundamental importance in chemical synthesis. Although many concepts for site-selective reactions are well established for solution chemistry, it is not a priori clear whether they can easily be transferred to reactions taking place on a metal surface. A metal will fix the chemical potential of the electrons and perturb the electronic states of the reactants because of ...

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Item type:Article
Date:8 April 2016
Institutions:Physics > Institute of Experimental and Applied Physics > Chair Professor Giessibl > Group Jascha Repp
Projects:GRK 1570, Elektronische Eigenschaften von Nanostrukturen auf Kohlenstoff-Basis
Identification Number:
ValueType
10.1021/jacs.5b13461DOI
27059121PubMed ID
Dewey Decimal Classification:500 Science > 530 Physics
500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33632
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