Direkt zum Inhalt

Hinreiner, Matthias ; Ryndyk, Dmitry ; Usvyat, Denis ; Merz, Thomas ; Schütz, Martin ; Richter, Klaus

Influencing the conductance in biphenyl-like molecular junctions with THz radiation

Hinreiner, Matthias, Ryndyk, Dmitry, Usvyat, Denis , Merz, Thomas, Schütz, Martin and Richter, Klaus (2013) Influencing the conductance in biphenyl-like molecular junctions with THz radiation. physica status solidi b 250 (11), pp. 2408-2416.

Date of publication of this fulltext: 19 Apr 2016 08:34
Article
DOI to cite this document: 10.5283/epub.33641


Abstract

We investigate the torsional vibrations in biphenyl-like molecular junctions and transport properties in the presence of an external THz field. Ab initio calculations including external electric fields show that the torsional angle of a thiolated biphenyl junction exhibits virtually no response. However, if functional groups are added to the molecule, creating a dipole moment in each of the ...

We investigate the torsional vibrations in biphenyl-like molecular junctions and transport properties in the presence of an external THz field. Ab initio calculations including external electric fields show that the torsional angle of a thiolated biphenyl junction exhibits virtually no response. However, if functional groups are added to the molecule, creating a dipole moment in each of the rings, an external field becomes more effective for changing . A model based on the cos2 phi dependence of the current for low bias voltages has been proposed for the biphenyl-like molecular junctions in presence of an external THz field including 2,2-bipyridine, 3,3-bipyridine, and 2,2,4,4-tetramethyl-3,3-bipyridine. The current through these molecules is shown to change if the THz frequency gets in resonance to the torsional vibration mode. Dithiolated bipyridine between gold leads in the presence of external THz radiation.



Involved Institutions


Details

Item typeArticle
Journal or Publication Titlephysica status solidi b
Publisher:WILEY-V C H VERLAG GMBH
Place of Publication:WEINHEIM
Volume:250
Number of Issue or Book Chapter:11
Page Range:pp. 2408-2416
Date24 October 2013
InstitutionsPhysics > Institute of Theroretical Physics > Chair Professor Richter > Group Klaus Richter
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Research Group Theoretical Chemistry > Prof. Dr. Martin Schütz
Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Research Group Theoretical Chemistry > PD Dr. Denis Usvyat
Identification Number
ValueType
10.1002/pssb.201349221DOI
1306.3872arXiv ID
KeywordsCONFORMATION; RECTIFIERS; TRANSPORT; BARRIER; ab initio methods; molecular electronics; nanoscale modeling; THz fields
Dewey Decimal Classification500 Science > 530 Physics
500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-336419
Item ID33641

Export bibliographical data

Owner only: item control page

nach oben