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Reactivity of Phosphaalkynes - Coordination, Cycloadditions and Subsequent Reactions

Rummel, Eva-Maria (2017) Reactivity of Phosphaalkynes - Coordination, Cycloadditions and Subsequent Reactions. PhD, Universität Regensburg.

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Date of publication of this fulltext: 24 Apr 2017 05:04

Abstract (German)

Diese Arbeit beschäftigt sich mit der Substanzklasse der Alkylidinphosphane - oder Phosphaalkine - und beschreibt deren Reaktivität gegenüber verschiedenen Übergangsmetallkomplexen und Zintl-Ionen. Hierbei wird auf die Koordination an Münzmetallkationen, die Cycloadditionsreaktionen zu 1,3-Diphosphetkomplexen und deren Folgereaktionen mit Silber(I)- und Gold(I)-salzen zu Koordinationsverbindungen eingegangen.

Translation of the abstract (English)

This work deals with the substance class of alkylidynephosphanes (or phosphaalkynes) and their reactivity towards various transition metal complexes and zintl ions. Herein, the coordination behaviour towards coinage metal salts, cycloaddition reactions leading to 1,3-diphosphete complexes is described as well as their subsequent reactions with silver(I) and gold(I) salts yielding coordination complexes.


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Item type:Thesis of the University of Regensburg (PhD)
Date:24 April 2017
Referee:Prof. Dr. Manfred Scheer
Date of exam:22 April 2016
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
Keywords:phosphaalkine, münzmetallkoordination, WCAs, diphosphete complexes
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33771
Owner only: item control page

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