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Metal-Free, Visible-Light-Mediated, Decarboxylative Alkylation of Biomass-Derived Compounds

Schwarz, Johanna ; König, Burkhard


Abstract

This work describes a mild, environmentally friendly method to activate natural carboxylic acids for decarboxylative alkylation. After esterification of biomass-derived acids to N-(acyloxy)phthalimides, the active esters are cleaved reductively by photocatalysis to give alkyl radicals, which undergo C–C bond formation with electron-deficient alkenes. This reaction is catalyzed by the organic dye ...

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