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A Step in Between: [Sn3Bi3]5− and Its Structural Relationship to [Sn3Bi5]3− and [Sn4Bi4]4−

Korber, Nikolaus and Friedrich, Ute (2016) A Step in Between: [Sn3Bi3]5− and Its Structural Relationship to [Sn3Bi5]3− and [Sn4Bi4]4−. Chemistry Open 5 (4), pp. 306-310.

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Date of publication of this fulltext: 24 Jun 2016 09:18

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Other URL: http://onlinelibrary.wiley.com/doi/10.1002/open.201600037/abstract


Abstract

Extraction of “RbSnBi” in liquid ammonia yielded the cluster anion [Sn3Bi5]3−, which could be crystallized in the compound [Rb@[2.2.2]crypt]3[Sn3Bi5]⋅8.87 NH3. This anion is found to be derived from the formerly reported [Sn4Bi4]4− by the formal substitution of one tin atom by bismuth. In contrast, the extraction of “RbSn2/Rb3Bi2” in liquid ammonia yielded the anion [Sn3Bi3]5− in the compound ...

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Item type:Article
Date:25 May 2016
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber
Projects:Open Access Publizieren (DFG)
Identification Number:
ValueType
10.1002/open.201600037DOI
Keywords:ammonia;cage molecules;polyanions;tinbismuthide;Zintl anions
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:33934
Owner only: item control page

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