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Synthesis, structure and photophysical properties of binuclear methylplatinum complexes containing cyclometalating 2-phenylpyridine or benzo{h}quinoline ligands: a comparison of intramolecular Pt–Pt and π–π interactions

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Jamali, S. ; Czerwieniec, Rafal ; Kia, Reza ; Jamshidi, Zahra ; Zabel, Manfred
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 25 Jul 2016 08:57


The binuclear cyclometalated complexes [Pt2Me2(ppy)2(μ-dppm)], 1a, and [Pt2Me2(bhq)2(μ-dppm)], 1b, in which ppy = 2-phenylpyridyl, bhq = benzo{h}quinoline and dppm = bis(diphenylphosphino)methane, were synthesized by the reaction of [PtMe(SMe2)(ppy)] or [PtMe(SMe2)(bhq)] with 1/2 equiv of dppm at room temperature, respectively. Complexes 1a and 1b were fully characterized by multinuclear (1H, ...


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