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Structure and bonding in three-coordinate N-heterocyclic carbene adducts of iron(II) bis(trimethylsilyl)amide

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Layfield, Richard A. ; McDouall, J. ; Scheer, Manfred ; Schwarzmaier, Christoph
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Date of publication of this fulltext: 26 Jul 2016 11:03


The molecular structures, chemical bonding and magnetochemistry of the three-coordinate iron(II) NHC complexes [(NHC)Fe{N(SiMe3)2}2] (NHC = IPr, 2; NHC = IMes, 3) are reported.

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