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Improvement of (bipy)Pt(XR)2 (X = O, S) type photosensitizers by covalent dye attachment

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Pevny, Florian ; Zabel, Manfred ; Winter, Rainer F. ; Rausch, Andreas ; Yersin, Hartmut
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 29 Jul 2016 06:22


Irradiation into the dye-based absorption band of complexes (tBu2bipy)Pt(SR)2 and (tBu2bipy)Pt(OR)2 where R denotes a coumarine-based thiolate and alkoxolate substituent populates the same excited triplet state as is obtained by excitation into the much weaker (RX)2Pt→tBu2bipy (X = O, S) charge-transfer band. This paves the way toward more efficient photosensitizers.

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