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Photodissociation dynamics of tert-butylnitrite following excitation to the S1 and S2 states. A study by velocity-map ion-imaging and 3D-REMPI spectroscopy

URN to cite this document:
urn:nbn:de:bvb:355-epub-341932
DOI to cite this document:
10.5283/epub.34193
Wenge, Andreas Maximilian ; Schmaunz, Andreas F. ; Kensy, Uwe ; Dick, Bernhard
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Date of publication of this fulltext: 02 Aug 2016 09:07


Abstract

Excitation of tert-butylnitrite into the first and second UV absorption bands leads to efficient dissociation into the fragment radicals NO and tert-butoxy in their electronic ground states 2Π and 2E, respectively. Velocity distributions and angular anisotropies for the NO fragment in several hundred rotational and vibrational quantum states were obtained by velocity-map imaging and the recently ...

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