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Vibrations and hydrogen bonding in porphycene

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Gawinkowski, S. ; Walewski, L. ; Vdovin, Alexander ; Slenczka, Alkwin
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 02 Aug 2016 06:28


Combined use of IR, Raman, neutron scattering and fluorescence measurements for porphycene isolated in helium nanodroplets, supersonic jet and cryogenic matrices, as well as for solid and liquid solutions, resulted in the assignments of almost all of 108 fundamental vibrations. The puzzling feature of porphycene is the apparent lack of the N–H stretching band in the IR spectrum, predicted to be ...


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