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Synthesis of heteroatomic Zintl anions in liquid ammonia – the new highly charged [Sn4Bi4]4− and fully ordered [Sn2Bi2]2−
Friedrich, Ute, Neumeier, Maria, Koch, Carina and Korber, Nikolaus (2012) Synthesis of heteroatomic Zintl anions in liquid ammonia – the new highly charged [Sn4Bi4]4− and fully ordered [Sn2Bi2]2−. Chemical Communications : ChemComm 48, pp. 10544-10546.Date of publication of this fulltext: 02 Aug 2016 06:27
Article
DOI to cite this document: 10.5283/epub.34195
Abstract
The new Zintl anion [Sn4Bi4]4−, synthesized by dissolving CsSnBi in liquid ammonia, forms a monocapped nortricyclane-like cage. Its electron localization function (ELF) analysis shows evidence for 3-centre bonding. The analogous reaction with KSnBi results in a crystallographically fully ordered tetrahedral [Sn2Bi2]2− ion.
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| Item type | Article | ||||
| Journal or Publication Title | Chemical Communications : ChemComm | ||||
| Publisher: | Royal Society of Chemistry | ||||
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| Open Access Type: | Alliance-/National licence | ||||
| Volume: | 48 | ||||
| Page Range: | pp. 10544-10546 | ||||
| Date | 2012 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber | ||||
| Identification Number |
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| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-341952 | ||||
| Item ID | 34195 |
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