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Enantioselective synthesis of (−)-paeonilide

URN to cite this document:
urn:nbn:de:bvb:355-epub-341981
DOI to cite this document:
10.5283/epub.34198
Harrar, Klaus ; Reiser, Oliver
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Date of publication of this fulltext: 02 Aug 2016 06:20



Abstract

The first enantioselective synthesis of (−)-paeonilide is reported. Starting from inexpensive furan-3-carboxylic acid the targeted monoterpene was obtained in 12 steps via an asymmetric cyclopropanation-lactonization cascade and a stereoselective side chain insertion at an acetal-like position.


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