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Fine-tuning the balance between crystallization and gelation and enhancement of CO2 uptake on functionalized calcium based MOFs and metallogels

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Mallick, Arijit ; Schön, Eva-Maria ; Panda, T. ; Sreenivas, K. ; Diaz Diaz, David ; Banerjee, R.
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 03 Aug 2016 08:11


The synthesis, structure, gas adsorption and catalytic properties of a new 3D porous, crystalline metal–organic framework (Ca-5TIA-MOF) as well as stable viscoelastic metallogels (Ca-5TIA-Gel) are reported. Remarkably, the preparation of both types of materials can be carried out starting from the same organic ligand (i.e. 5-(1,2,4-triazoleyl)isophthalic acid (5TIA)), divalent metal ion (i.e. ...


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