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Stoichiometry-controlled FeP nanoparticles synthesized from a single source precursor

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Hunger, Cornelia ; Ojo, Wilfried-Solo ; Bauer, Susanne ; Xu, Shu ; Zabel, Manfred ; Chaudret, Bruno ; Lacroix, Lise-Marie ; Scheer, Manfred
License: Allianz- bzw. Nationallizenz
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Date of publication of this fulltext: 03 Aug 2016 10:57


Phase-pure FeP nanoparticles (NPs) have been synthesized through low temperature thermolysis of the single source precursor [(CO)4Fe(PH3)]. Examination of the mechanism demonstrates the central role of the labile CO ligands and the weak P–H bonds to yield stoichiometry controlled FeP materials.

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