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P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

Li, Tianshu, Gamer, Michael T., Scheer, Manfred, Konchenko, Sergei N. and Roesky, Peter W. (2013) P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes. Chemical Communications 49, pp. 2183-2185.

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Date of publication of this fulltext: 03 Aug 2016 08:17

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The two new 3d/4f polyphosphide complexes [(Cp*Fe)2P10{Sm(η5-C5Me4R)2}2] (Cp* = η5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(η5-P5)] with samarocenes. They are the first P10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.

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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34222
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