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P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes
Article
Li, Tianshu, Gamer, Michael T., Scheer, Manfred
, Konchenko, Sergei N. and Roesky, Peter W.
(2013)
P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes.
Chemical Communications 49, pp. 2183-2185.
DOI to cite this document: 10.5283/epub.34222
Abstract
The two new 3d/4f polyphosphide complexes [(Cp*Fe)(2)P-10{Sm-(eta(5)-C5Me4R)(2)}(2)] (Cp* = eta 5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(eta(5)-P-5)] with samarocenes. They are the first P-10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.
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| Item type | Article | ||||
| Journal or Publication Title | Chemical Communications | ||||
| Publisher | ROYAL SOC CHEMISTRY | ||||
| Open Access Type | Alliance-/National licence | ||||
| Place of Publication | CAMBRIDGE | ||||
| Volume | 49 | ||||
| Page Range | pp. 2183-2185 | ||||
| Date | 2013 | ||||
| Date of publication | 03 Aug 2016 08:17 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Chair Prof. Dr. Manfred Scheer | ||||
| Identification Number |
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| Keywords | P-4 ACTIVATION; COMPLEXES; ELEMENTS; LIGANDS; | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-342225 | ||||
| Item ID | 34222 |
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