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P–P bond formation via reductive dimerization of [Cp*Fe(η5-P5)] by divalent samarocenes

URN to cite this document:
urn:nbn:de:bvb:355-epub-342225
Li, Tianshu ; Gamer, Michael T. ; Scheer, Manfred ; Konchenko, Sergei N. ; Roesky, Peter W.
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Date of publication of this fulltext: 03 Aug 2016 08:17


Abstract

The two new 3d/4f polyphosphide complexes [(Cp*Fe)2P10{Sm(η5-C5Me4R)2}2] (Cp* = η5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(η5-P5)] with samarocenes. They are the first P10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.


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