| License: Allianz- bzw. Nationallizenz PDF - Published Version (2MB) |
- URN to cite this document:
- urn:nbn:de:bvb:355-epub-342225
- DOI to cite this document:
- 10.5283/epub.34222
Alternative links to fulltext:DOI
Abstract
The two new 3d/4f polyphosphide complexes [(Cp*Fe)2P10{Sm(η5-C5Me4R)2}2] (Cp* = η5-C5Me5; R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(η5-P5)] with samarocenes. They are the first P10 bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.
Owner only: item control page