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Reaction of Sn44− in liquid ammonia: the formation of Rb6[(η2-Sn4)Zn(η3-Sn4)]·5NH3
Fendt, Franziska, Koch, Carina, Gärtner, Stefanie and Korber, Nikolaus
(2013)
Reaction of Sn44− in liquid ammonia: the formation of Rb6[(η2-Sn4)Zn(η3-Sn4)]·5NH3.
Dalton Transactions 42, pp. 15548-15550.
Date of publication of this fulltext: 04 Aug 2016 11:05
Article
DOI to cite this document: 10.5283/epub.34232
Abstract
The reaction of Rb4Sn4 with ZnPh2 in liquid ammonia in the presence of [2.2.2]-cryptand yielded crystals of Rb-6[(eta(2)-Sn-4)Zn(eta(3)-Sn-4)]center dot 5NH(3), which could be characterized by single crystal X-ray diffraction. This is the first example of a successful solution reaction of the highly charged tetrahedral Sn-4(4-) anions. The homoleptic [E4ZnE4](6-) complex (E = tetrel element) was previously known only for E=Ge and Si/Ge.
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| Item type | Article | ||||
| Journal or Publication Title | Dalton Transactions | ||||
| Publisher: | ROYAL SOC CHEMISTRY | ||||
|---|---|---|---|---|---|
| Place of Publication: | CAMBRIDGE | ||||
| Volume: | 42 | ||||
| Page Range: | pp. 15548-15550 | ||||
| Date | 2013 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Anorganische Chemie Chemistry and Pharmacy > Institut für Anorganische Chemie > Arbeitskreis Prof. Dr. Nikolaus Korber | ||||
| Identification Number |
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| Keywords | GROUP 15 ELEMENTS; CRYSTAL-STRUCTURE; ZINTL PHASE; TETRAHEDRO-TETRASTANNIDE; SOLUTION CHEMISTRY; CLUSTERS; RB; REFINEMENT; IONS; CS; | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-342321 | ||||
| Item ID | 34232 |
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