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Luminescent gold–silver complexes derived from neutral bis(perfluoroaryl)diphosphine gold(I) precursors

Bojan, R. Vilma, Czerwieniec, Rafal, Laguna, A., Lasanta, T., López-de-Luzuriaga, José M., Monge, Miguel, Olmos, M. Elena and Yersin, Hartmut (2013) Luminescent gold–silver complexes derived from neutral bis(perfluoroaryl)diphosphine gold(I) precursors. Dalton Transactions 42, pp. 4267-4277.

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Abstract

Complex [Au{4-C6F4(4-C6BrF4)}(tht)] reacts with diphosphines (L–L) such as bis(diphenylphosphino)methane (dppm) or 1,2-bis(diphenylphosphino)benzene (dppb) in a 2 : 1 molar ratio in dichloromethane, leading to neutral products of stoichiometry [(Au{4-C6F4(4-C6BrF4)})2(μ-L–L)] (L–L = dppm (1), dppb (2)). In the crystal structure of complex 2 short Au⋯Au interactions of 2.9367(5) and 2.9521(5) Å ...

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Item type:Article
Date:2013
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Hartmut Yersin
Identification Number:
ValueType
10.1039/c2dt32973eDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34234
Owner only: item control page

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