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Morphologies Observed in Ultraflexible Microemulsions with and without the Presence of a Strong Acid

Lopian, Tobias ; Schöttl, Sebastian ; Prevost, Sylvain ; Pellet-Rostaing, Stephane ; Horinek, Dominik ; Kunz, Werner ; Zemb, Thomas


We show that three different morphologies exist near the two-phase boundary of ternary systems containing a hydrotropic cosolvent. Based on synchrotron small-and wide-angle X-ray scattering combined with molecular dynamics, we rationalize the specific scattering signature of direct, bicontinuous, and reverse mesoscale solubilization. Surprisingly, these mesostructures are resilient toward strong ...


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