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Metal-Free Photocatalyzed Cross Coupling of Bromoheteroarenes with Pyrroles

Marzo, Leyre, Ghosh, Indrajit, Esteban, Francisco and König, Burkhard (2016) Metal-Free Photocatalyzed Cross Coupling of Bromoheteroarenes with Pyrroles. ACS Catalysis 6, pp. 6780-6784.

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The excited radical anion of rhodamine 6G reduces heteroaryl bromides and chlorides to generate heteroaryl radicals that were successively trapped by pyrroles for the synthesis of heteroaromatic biaryls in moderate to excellent yields. The synthetically important photoredox catalytic C−H heteroarylation reaction works for a broad range of brominated electron-rich heteroarenes and chlorinated ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
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Keywords:photoredox catalysis, visible light, C−H heteroarylation, metal-free reaction, pyrrole
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:34645
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