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Visible-Light Photo-Arbuzov Reaction of Aryl Bromides and Trialkyl Phosphites Yielding Aryl Phosphonates

Shaikh, Rizwan ; Düsel, Simon J. S. ; König, Burkhard



Abstract

Aryl phosphonates are functional groups frequently found in pharmaceutical and crop protection agents. For their synthesis via C-P bond formation typically transition-metal-catalyzed reactions are used. We report a visible-light photo-Arbuzov reaction as an efficient, mild, and metal-free alternative. Rhodamine 6G (Rh.6G) is used as the photocatalyst, generating aryl radicals under blue light. ...

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