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Photocatalytic oxidation of sulfinates to vinyl sulfones with cyanamide-functionalised carbon nitride

Meyer, Andreas Uwe , Lau, Vincent Wing-hei , König, Burkhard and Lotsch, Bettina V. (2017) Photocatalytic oxidation of sulfinates to vinyl sulfones with cyanamide-functionalised carbon nitride. European Journal of Organic Chemistry, pp. 2179-2185.

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Abstract

The cyanamide-functionalised carbon nitride (NCN-CNx) can be employed as a photo-redox catalyst for the light-induced sulfonylation of alkenes with sulfinate salts, attaining product yields twice those obtained with the non-functionalised counterpart and comparable to those achieved with the benchmark homogeneous photocatalyst Eosin Y. NCN-CNx as a heterogeneous photocatalyst is easily isolatable ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1002/ejoc.201601637DOI
Keywords:LIGHT PHOTOREDOX CATALYSIS; VISIBLE-LIGHT; ORGANIC-SYNTHESIS; HYDROGEN-PRODUCTION; CHEMICAL-SHIFTS; H-2 PRODUCTION; NI CATALYST; EOSIN Y; COMPLEXES; GENERATION; Heterogeneous catalysis; Photocatalysis; Alkenes; Sulfonylation; Reaction mechanisms; Oxidation
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:35168
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