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Photocatalytic oxidation of sulfinates to vinyl sulfones with cyanamide-functionalised carbon nitride

Meyer, Andreas Uwe ; Lau, Vincent Wing-hei ; König, Burkhard ; Lotsch, Bettina V.


The cyanamide-functionalised carbon nitride (NCN-CNx) can be employed as a photo-redox catalyst for the light-induced sulfonylation of alkenes with sulfinate salts, attaining product yields twice those obtained with the non-functionalised counterpart and comparable to those achieved with the benchmark homogeneous photocatalyst Eosin Y. NCN-CNx as a heterogeneous photocatalyst is easily isolatable ...


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