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Nitrosonium-Mediated Phenol–Arene Cross-Coupling Involving Direct C–H Activation

Eisenhofer, Anna, Wille, Uta and König, Burkhard (2017) Nitrosonium-Mediated Phenol–Arene Cross-Coupling Involving Direct C–H Activation. Australian Journal of Chemistry 70, pp. 407-412.

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Abstract

The nitrosonium ion (NO+) is a highly versatile nitration and nitrosation reagent, as well as a strong one-electron oxidant. Herein, we describe an environmentally benign and mild method for the in situ formation of NO+ from readily available inorganic nitrate salts, i.e. lithium nitrate, through a finely tuned interplay between formic acid and MeOH, which are used as the solvent system. This ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1071/CH16622DOI
Keywords:AROMATIC NITRATION; ELECTRON-TRANSFER; PHOTOREDOX CATALYSIS; NITROGEN-DIOXIDE; NO3 RADICALS; FORMIC-ACID; CHEMISTRY; CATION; FLUOROALCOHOLS; ACETONITRILE;
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Partially
Item ID:35238
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