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Conformational Preferences in Small Peptide Models: The Relevance of cis/trans-Conformations

Jangra, H. ; Haindl, M. H. ; Achrainer, F, ; Hioe, J. ; Gschwind, Ruth Maria ; Zipse, H.


The accurate description of cis/trans peptide structures is of fundamental relevance for the field of protein modeling and protein structure determination. A comprehensive conformational analysis of dipeptide model Ace-GlyNMe (1) has been carried out by using a combination of theoretical calculations and experimental (H-1 and C-13 NMR and NOESY) spectroscopic measurements to assess the relevance ...


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