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NMR Spectroscopic Characterization of Charge Assisted Strong Hydrogen Bonds in Brønsted Acid Catalysis

Sorgenfrei, N., Hioe, J., Greindl, J., Rothermel, K., Morana, F., Lokesh, N. and Gschwind, Ruth Maria (2016) NMR Spectroscopic Characterization of Charge Assisted Strong Hydrogen Bonds in Brønsted Acid Catalysis. Journal of the American Chemical Society 138 (50), pp. 16345-16354.

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Date of publication of this fulltext: 16 Mar 2017 08:46

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Other URL: http://dx.doi.org/10.1021/jacs.6b09243


Abstract

Hydrogen bonding plays a crucial role in Brønsted acid catalysis. However, the hydrogen bond properties responsible for the activation of the substrate are still under debate. Here, we report an in depth study of the properties and geometries of the hydrogen bonds in (R)-TRIP imine complexes (TRIP: 3,3′-Bis(2,4,6-triisopropylphenyl)-1,1′-binaphthyl-2,2′-diylhydrogen phosphate). From NMR ...

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Item type:Article
Date:2016
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Identification Number:
ValueType
10.1021/jacs.6b09243DOI
27936674PubMed ID
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:35400
Owner only: item control page

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