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Synthesis of Arylated Nucleobases by Visible Light Photoredox

Graml, Andreas ; Ghosh, Indrajit ; König, Burkhard


Arylated nucleobases were synthesized by visible light photocatalysis using rhodamine 6G as photoredox catalyst and N,N-diisopropylethylamine as sacrificial electron donor. The high redox potential of this catalyst system is achieved by a consecutive photoinduced electron transfer process (conPET) and allows the room temperature conversion of brominated and chlorinated nucleobases or nucleobase ...


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