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A systematic study of the influence of mesoscale structuring on the kinetics of a chemical reaction

Krickl, Sebastian ; Buchecker, Thomas ; Meyer, Andreas Uwe ; Grillo, Isabelle ; Touraud, Didier ; Bauduin, Pierre ; König, Burkhard ; Pfitzner, Arno ; Kunz, Werner


In this contribution, we (i) link the mesoscopic structuring of the binary structured solvent mixture H2O/tert-butanol (TBA) to the kinetics and the efficacy of the oxidation of benzyl alcohol (BA) to the corresponding aldehyde catalyzed by H5PMo12V2O40. We also compare the catalytic efficacy of this reaction in the mesoscopically structured solvent H2O/TBA to an unstructured (or very weakly ...


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