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Enantiomerically pure pentagonal-bipyramidal metal complexes with predetermined helicity in the solid and the solution state

Seitz, Michael, Kaiser, Anja, Stempfhuber, Sabine, Zabel, Manfred and Reiser, Oliver (2005) Enantiomerically pure pentagonal-bipyramidal metal complexes with predetermined helicity in the solid and the solution state. Inorganic Chemistry 44 (13), pp. 4630-4636.

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Other URL: http://dx.doi.org/10.1021/ic050014b


Abstract

New metal complexes with pentagonal-bipyramidal geometry have been synthesized with the chiral, pentadentate bis(oxazoline) ligand (R,R)-1, including the metal ions magnesium(II), iron(II), and cadmium(II). In the solid state, a complete transfer of chirality from the ligand is observed to exclusively yield enantiomerically pure P-helical, isostructural pentagonal bipyramidal complexes, as ...

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Item type:Article
Date:27 June 2005
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Oliver Reiser
Identification Number:
ValueType
10.1021/ic050014bDOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Item ID:358
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