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Enantiomerically pure pentagonal-bipyramidal metal complexes with predetermined helicity in the solid and the solution state

Seitz, Michael ; Kaiser, Anja ; Stempfhuber, Sabine ; Zabel, Manfred ; Reiser, Oliver



Abstract

New metal complexes with pentagonal-bipyramidal geometry have been synthesized with the chiral, pentadentate bis(oxazoline) ligand (R,R)-1, including the metal ions magnesium(II), iron(II), and cadmium(II). In the solid state, a complete transfer of chirality from the ligand is observed to exclusively yield enantiomerically pure P-helical, isostructural pentagonal bipyramidal complexes, as ...

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