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Carboxylation of Aromatic and Aliphatic Bromides and Triflates with CO2 by Dual Visible-Light–Nickel Catalysis

Meng, Qing-Yuan, Wang, Shun and König, Burkhard (2017) Carboxylation of Aromatic and Aliphatic Bromides and Triflates with CO2 by Dual Visible-Light–Nickel Catalysis. Angewandte Chemie International Edition 56, pp. 13426-13430.

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Abstract

We report the efficient carboxylation of bromides and triflates with K2CO3 as the source of CO2 in the presence of an organic photocatalyst in combination with a nickel complex under visible light irradiation at room temperature. The reaction is compatible with a variety of functional groups and has been successfully applied to the synthesis and derivatization of biologically active molecules. In ...

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Item type:Article
Date:2017
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 1626 Chemische Photokatalyse
Identification Number:
ValueType
10.1002/anie.201706724DOI
Keywords:TRANSITION-METAL-COMPLEXES; CARBON-DIOXIDE; PHOTOREDOX CATALYSIS; ORGANONICKEL COMPLEXES; DRIVEN CARBOXYLATION; ORGANIC-SYNTHESIS; ELECTRON-TRANSFER; ALLYLIC ALCOHOLS; BONDS; PALLADIUM; carbon dioxide; carboxylation; nickel catalysis; photocatalysis; visible light
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:36196
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