Abstract
We have reported in our recent Communication the
advantages of combining the best features of visible light
absorbing tris(2,2’-bipyridine)ruthenium(II), Ru(bpy)3
2+, and visible light transparent, however, strongly reducing, polycyclic aromatic hydrocarbons via a simple triplet–triplet
energy transfer process in synthetic photoredox catalysis.
Balzani, Ceroni et al. question in their ...
Abstract
We have reported in our recent Communication the
advantages of combining the best features of visible light
absorbing tris(2,2’-bipyridine)ruthenium(II), Ru(bpy)3
2+, and visible light transparent, however, strongly reducing, polycyclic aromatic hydrocarbons via a simple triplet–triplet
energy transfer process in synthetic photoredox catalysis.
Balzani, Ceroni et al. question in their Correspondence
the formation of a pyrene radical anion as proposed reactive
intermediate, as the electron transfer from the amine to
a pyrene triplet state is endothermic based on the estimated
values derived from literature redox potentials.
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