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Steinleitner, Philipp ; Merkl, Philipp ; Nagler, Philipp ; Mornhinweg, Joshua ; Schüller, Christian ; Korn, Tobias ; Chernikov, Alexey ; Huber, Rupert

Direct Observation of ultrafast exciton Formation in a monolayer of WSe2

Steinleitner, Philipp, Merkl, Philipp, Nagler, Philipp, Mornhinweg, Joshua, Schüller, Christian, Korn, Tobias , Chernikov, Alexey und Huber, Rupert (2017) Direct Observation of ultrafast exciton Formation in a monolayer of WSe2. Nano Letters 17, S. 1455-1460.

Veröffentlichungsdatum dieses Volltextes: 02 Nov 2017 14:37
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.36260


Zusammenfassung

Many of the fundamental optical and electronic properties of atomically thin transition metal dichalcogenides are dominated by strong Coulomb interactions between electrons and holes, forming tightly bound atom-like states called excitons. Here, we directly trace the ultrafast formation of excitons by monitoring the absolute densities of bound and unbound electron hole pairs in single monolayers ...

Many of the fundamental optical and electronic properties of atomically thin transition metal dichalcogenides are dominated by strong Coulomb interactions between electrons and holes, forming tightly bound atom-like states called excitons. Here, we directly trace the ultrafast formation of excitons by monitoring the absolute densities of bound and unbound electron hole pairs in single monolayers of WSe2 on a diamond substrate following femtosecond nonresonant optical excitation. To this end, phase locked mid-infrared probe pulses and field-sensitive electro-optic sampling are used to map out the full complex-valued optical conductivity of the nonequilibrium system and to discern the hallmark low-energy responses of bound and unbound pairs. While the spectral shape of the infrared response immediately after above-bandgap injection is dominated by free charge carriers, up to 60% of the electron-hole pairs are bound into excitons already on a subpicosecond time scale, evidencing extremely fast and efficient exciton formation. During the subsequent recombination phase, we still find a large density of free carriers in addition to excitons, indicating a nonequilibrium state of the photoexcited electron-hole system.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftNano Letters
Verlag:AMER CHEMICAL SOC
Ort der Veröffentlichung:WASHINGTON
Band:17
Seitenbereich:S. 1455-1460
Datum2017
InstitutionenPhysik > Institut für Experimentelle und Angewandte Physik > Lehrstuhl Professor Huber > Arbeitsgruppe Rupert Huber
Physik > Institut für Experimentelle und Angewandte Physik > Lehrstuhl Professor Lupton > Arbeitsgruppe Christian Schüller
Identifikationsnummer
WertTyp
10.1021/acs.nanolett.6b04422DOI
Stichwörter / KeywordsTRANSITION-METAL DICHALCOGENIDES; GIANT BANDGAP RENORMALIZATION; TUNGSTEN DISULFIDE; MOS2; PHOTOLUMINESCENCE; HETEROSTRUCTURES; EXCITATION; LINEWIDTH; DYNAMICS; STATES; Dichalcogenides; atomically thin 2D crystals; exciton formation; ultrafast dynamics
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-362605
Dokumenten-ID36260

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