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Direct Observation of ultrafast exciton Formation in a monolayer of WSe2
Steinleitner, Philipp, Merkl, Philipp, Nagler, Philipp, Mornhinweg, Joshua, Schüller, Christian, Korn, Tobias
, Chernikov, Alexey and Huber, Rupert
(2017)
Direct Observation of ultrafast exciton Formation in a monolayer of WSe2.
Nano Letters 17, pp. 1455-1460.
Date of publication of this fulltext: 02 Nov 2017 14:37
Article
DOI to cite this document: 10.5283/epub.36260
Abstract
Many of the fundamental optical and electronic properties of atomically thin transition metal dichalcogenides are dominated by strong Coulomb interactions between electrons and holes, forming tightly bound atom-like states called excitons. Here, we directly trace the ultrafast formation of excitons by monitoring the absolute densities of bound and unbound electron hole pairs in single monolayers ...
Many of the fundamental optical and electronic properties of atomically thin transition metal dichalcogenides are dominated by strong Coulomb interactions between electrons and holes, forming tightly bound atom-like states called excitons. Here, we directly trace the ultrafast formation of excitons by monitoring the absolute densities of bound and unbound electron hole pairs in single monolayers of WSe2 on a diamond substrate following femtosecond nonresonant optical excitation. To this end, phase locked mid-infrared probe pulses and field-sensitive electro-optic sampling are used to map out the full complex-valued optical conductivity of the nonequilibrium system and to discern the hallmark low-energy responses of bound and unbound pairs. While the spectral shape of the infrared response immediately after above-bandgap injection is dominated by free charge carriers, up to 60% of the electron-hole pairs are bound into excitons already on a subpicosecond time scale, evidencing extremely fast and efficient exciton formation. During the subsequent recombination phase, we still find a large density of free carriers in addition to excitons, indicating a nonequilibrium state of the photoexcited electron-hole system.
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| Item type | Article | ||||
| Journal or Publication Title | Nano Letters | ||||
| Publisher: | AMER CHEMICAL SOC | ||||
|---|---|---|---|---|---|
| Place of Publication: | WASHINGTON | ||||
| Volume: | 17 | ||||
| Page Range: | pp. 1455-1460 | ||||
| Date | 2017 | ||||
| Institutions | Physics > Institute of Experimental and Applied Physics > Chair Professor Huber > Group Rupert Huber Physics > Institute of Experimental and Applied Physics > Chair Professor Lupton > Group Christian Schüller | ||||
| Identification Number |
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| Keywords | TRANSITION-METAL DICHALCOGENIDES; GIANT BANDGAP RENORMALIZATION; TUNGSTEN DISULFIDE; MOS2; PHOTOLUMINESCENCE; HETEROSTRUCTURES; EXCITATION; LINEWIDTH; DYNAMICS; STATES; Dichalcogenides; atomically thin 2D crystals; exciton formation; ultrafast dynamics | ||||
| Dewey Decimal Classification | 500 Science > 530 Physics | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-362605 | ||||
| Item ID | 36260 |
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