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Tuning the Thermal Isomerization of Phenylazoindole Photoswitches from Days to Nanoseconds

Simeth, Nadja Anita ; Crespi, Stefano ; Fagnoni, Maurizio ; König, Burkhard


The growing interest in light-driven molecular switches and optical oscillators led to the development of molecules that are able to interconvert from a stable to a metastable configuration upon photochemical triggering and to return to the thermodynamically stable form as soon as the light stimulus is removed. Controlling a wide range of back-isomerization lifetimes in the dark is a crucial goal ...


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